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Thursday, August 13, 2020 | History

5 edition of Volumetric Properties of Electrolyte Solutions found in the catalog.

Volumetric Properties of Electrolyte Solutions

Estimation Methods and Experimental Data

by G. G. Aseyev

  • 190 Want to read
  • 29 Currently reading

Published by Begell House Publishers .
Written in English

    Subjects:
  • Tables,
  • Electrochemistry,
  • Science,
  • Science/Mathematics,
  • SCI,
  • SCI013050,
  • Chemistry - Physical & Theoretical,
  • Electrolyte solutions

  • The Physical Object
    FormatHardcover
    Number of Pages1572
    ID Numbers
    Open LibraryOL8672113M
    ISBN 10156700072X
    ISBN 109781567000726

    Volumetric Properties: Liquids, Solutions, and Vapors. This new project is a companion to an earlier IUPAC project Heat Capactities: Liquids Solutions, and Vapors, which was published as a book with the same name by the Royal Society of Chemistry in (ISBN ). Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

      This classic text, originally published in the s, remains a standard reference in the literature of physical chemistry. Its focus on the fundamental properties of electrolyte solutions ensures its enduring relevance, and its substantial body of fact and theory continues to offer vital information for the interpretation of data. The authors present their material in a pattern of alternate 5/5(1). Chapter 3 deals with the volumetric properties of aqueous electrolyte solutions. Different theoretical approaches for description of these properties are discussed.

    About Features. NEW TO THIS EDITION. NEW - Expands discussion of the theoretical concepts used to describe and interpret solution ___ NEW - Now covers models such as the lattice fluid theory and the statistical associated fluid theory (SAFT).Pg.___ NEW - Offers a new chapter on polymer solutions that includes discussions of gas-polymer equilibria at ordinary and high pressures. Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources Reviews: 1.


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Volumetric Properties of Electrolyte Solutions by G. G. Aseyev Download PDF EPUB FB2

Get this from a library. Volumetric properties of electrolyte solutions: estimation methods and experimental data. [G G Aseev; Ivan Dmitrievich Zaĭt︠s︡ev]. Volumetric Properties of Electrolyte Solutions: Estimation Methods and Experimental Data By G. Aseyev and I. Zaytsev (Khar'kov Research Institute of Basic Chemistry).

Begell House: New York. $ ISBN X. Electrolyte Solutions In the last few chapters of this book, we will deal with several speci c types of chemical systems. The rst one is solutions and equilibria involving electrolytes, which we will take up in this chapter.

The thermodynamics of electrolyte so-lutions is important for a large number of chemical systems, such as acid-baseFile Size: KB. in electrolyte solutions is of importance in many pollution abatement processes. The influence of salts on the vapor pressure of aqueous solutions of organic material may be important for the proper choice of a separation process.

Salts may even introduce a liquid-liquid phase splitting in aqueous solutions of organic Size: 1MB. Thermodynamic Properties of Aqueous Electrolyte Solutions.

Volumetric and Compressibility Studies in molkg−1, molkg−1, and molkg−1 Sodium Carbonate and Sodium Sulfate Solutions at Temperatures from K to K†Cited by: 8. The research of this dissertation has focused on the volumetric properties of electrolyte solutions, including seawater, across wide ranges of temperature and concentration.

The volume and compressibility are inherently useful as physical chemical properties of electrolyte solutions. They are directly related to the density and. PDF | The ion interaction approach developed by Pitzer allows the prediction of thermodynamic characteristics of mixed electrolyte solutions at various | Find, read and cite all the research.

Volumetric Properties of Mixed Electrolyte Aqueous Solutions at Elevated Temperatures and Pressures. The System KCl−NaCl−H 2 O to K, 40 MPa, and Ionic Strength from ( to ) molkg. @article{osti_, title = {Volumetric properties of aqueous sodium chloride solutions}, author = {Rogers, P S.Z. and Pitzer, K S}, abstractNote = {Literature data for the volumetric properties of sodium chloride solutions to concentrations of molal have been compiled and critically evaluated.

A semi-empirical equation of the same type found to be effective in describing the thermal. Fig. 1, Fig. 2 show that the AMV of glucose is always higher in an electrolyte solution compared to water.

Moreover, for a given molality of glucose, the AMV increases with the electrolyte concentration. The variation of the AMV of the saccharides in electrolyte solutions can be interpreted from the structural hydration model, based on the co-sphere concept developed by by: The number of moles of dissolved particles is greater for electrolyte solutions, so there will be a greater impact on colligative properties.

Vapor Pressure Vapor pressure is the pressure exerted by a vapor in equilibrium with its condensed phase, either liquid or solid, at a particular temperature. Abstract. The volumetric properties of aqueous sodium chloride solutions from 0/sup 0/ to /sup 0/C at pressures up to bars for concentrations ranging from infinite dilution to as high as molal were obtained by a computer regression of the available experimental data from the by: Volumetrie properties of concentrated electrolyte solutions Z.

KODEJŠ and P. PACÁK Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, CS 00 Prague Received 13 May The paper presents a brief review of the current views, theories, and models in the field of molar volumes of highly concentrated electrolyte solutions.

This classic text, originally published in the s, remains a standard reference in the literature of physical chemistry. Its focus on the fundamental properties of electrolyte solutions ensures its enduring relevance, and its substantial body of fact and theory continues to offer vital information for the interpretation of data/5(5).

Volume Properties - Liquids, Solutions and Vapours Details Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the literature.

The book contains the very latest information on all aspects of volume properties related to liquids and vapours, either pure or mixed. The chapters, all written by acknowledged experts in their respective fields, cover theory, experimental methods and techniques and results on all types of Pages: ISBN: OCLC Number: Description: xix, pages: illustrations ; 25 cm: Contents: Volumetric Properties: Introduction, Concepts and Selected Applications; Experimental Techniques 1: Direct Methods ; Experimental Techniques 2: Vibrating Tube Densimetry ; Density Standards and Traceability; Volumetric Properties from Multiparameter Equations of State.

The volumetric properties of aqueous solutions containing non-electrolytes have been determined by density measurements in the temperature range –25 °C. Linear polyols CHOH(CHOH)CHOH with = 2–4 (= 4 has three diasteroisomers), -inositol and t-butylurea.

Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the ting a collection of concise, focused chapters, this book offers a comprehensive guide to the latest developments in the field and a starting point for more detailed research.

Ternary systems (amino acid + ionic liquid + H 2 O) are considered. Volumetric properties including density, V φ, ΔV φ 0 and E φ 0 are determined.

Glycine and l-serine were amino acids and [Emim][HSO 4] was IL studied. V φ values for amino acids increased with both concentration of amino acids and temperature.

Both studied amino acids act as structure maker in ternary by:. calculate freezing point depression, boiling point elevation and solution molality of non electrolyte solutions See sample problems in book and work through all of them, page on Calculate the expected change in freezing point of water in a solution of g of.

The density of aqueous solutions of LiF, NaF, or KF, at room temperature, is measured as a function of the concentration.

The measurements, together with corresponding data available on other alkali halides, are used to illustrate the concentration dependence of the apparent molar volume of the electrolytes in aqueous solution. The data is in accordance with the conception that an essential Cited by:   Rowland, D.: Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions.

Talanta90–92 () CrossRef PubMed Google Scholar Cited by: 1.